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JCP Spotlight Collection

 Cold and Ultracold Molecules: Spotlight on Orbiting Resonances
David W. Chandler
Sandia National Laboratories

Chandler Interview (MP3)

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Abstract  There is great interest in the production of cold molecules, at temperatures below 1 K, and ultracold molecules, at temperatures below 1 mK. Such molecules have potential applications in areas ranging from precision measurement to quantum information storage and processing, and quantum gases of ultracold polar molecules are expected to exhibit novel quantum phases. In addition, cold molecules open up a new domain for collision physics, dominated by long-range forces and scattering resonances. There have been major recent advances both in cooling molecules from room temperature and in forming molecules in ultracold atomic gases. As these techniques mature and cold and ultracold samples are more accessible collision studies at previously unavailable energies will be possible. This spotlight article will highlight some of the background and motivation for studying collisions at low energies and will direct readers to recent articles on the recent experimental advancements.

J. Chem. Phys. 132, 110901 (2010)

   

Highlighted References

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Rotational predissociation, vibrational mixing, and van der Waals intermolecular potentials of NeDF
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State‐to‐state measurements of internal rotational predissociation in OH–Ar (A 2Σ+)
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Predissociation dynamics on a highly anisotropic potential: OH–Ar (A 2Σ+)
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A close-coupling study of vibrational-rotational quenching of CO by collision with hydrogen atoms
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Observation of orbiting resonances in the integral cross section of H-Xe
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Vibrational relaxation of CO by collisions with 4He at ultracold temperatures
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Quantum dynamics of the O+OH→H+O2 reaction at low temperatures
Q. G. N. Balakrishnan and B. K. Kendrick, J. Chem. Phys. 129, 224309 (2008).

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Interaction of NH(X 3Σ-) with He: Potential energy surface, bound states, and collisional Zeeman relaxation
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The He–CaH(2Σ+) interaction. II. Collisions at cold and ultracold temperatures
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Interactions and dynamics in Li+Li2 ultracold collisions
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O+OH→O2+H: A key reaction for interstellar chemistry. New theoretical results and comparison with experiment
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