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J. Chem. Phys. 124, 214107 (2006); http://dx.doi.org/10.1063/1.2194905 (13 pages)
Multipole-multimode Floquet theory of rotational resonance width experiments: 
– distance measurements in uniformly labeled solids
Francis Bitter Magnet Laboratory, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 and Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139
(Received 3 February 2006; accepted 20 March 2006; published online 7 June 2006)
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Add to Facebook– distance measurements that are based on ZQ-magnetization exchange processes in rotational resonance width experiments. With suitable examples drawn from measurements in N-acetyl-[U-,
]-L-valine-L-leucine, we substantiate our approach and propose methods for improving the accuracy and reliability of such – distance measurements in uniformly , -labeled solids. In addition, the theoretical model presented in this article provides a more general framework for describing relaxation phenomena involving multiple decay rate constants in zero-quantum processes.© 2006 American Institute of Physics
Article Outline
- INTRODUCTION
- THEORY
- Basic theory
- Spin dynamics using the MMFT approach
- RESULTS AND DISCUSSION
- CONCLUSIONS
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