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J. Chem. Phys. 117, 55 (2002); http://dx.doi.org/10.1063/1.1481758 (4 pages)
On the oscillator strength sums S(±1) of atoms and ions
(Received 13 March 2002; accepted 8 April 2002)
Using rigorous relations discovered recently, the Hartree–Fock limit values of the dipole oscillator strength sums S(−1) and S(+1) are obtained for the 102 neutral atoms He through Lr, singly charged 53 cations Li+ through Cs+, and 43 stable anions H− through I− in their experimental ground states. The present results for the ionic species are the first compilation of the sums. For heavy neutral atoms, the literature S(+1) values are found to be insufficiently accurate. © 2002 American Institute of Physics.
© 2002 American Institute of Physics
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