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Journal of Chemical Physics / Volume 119 / Issue 1 / ARTICLES / Gas Phase Dynamics and Structure: Spectroscopy, Molecular Interactions, Scattering, and Photochemistry

J. Chem. Phys. 119, 224 (2003); http://dx.doi.org/10.1063/1.1577311 (8 pages)

Photodissociation of oriented HXeI molecules generated from HI–Xen clusters

N. Hendrik Nahler1, Reinhard Baumfalk1, Udo Buck1, Zsolt Bihary2, R. Benny Gerber2,3, and Bretislav Friedrich4

1Max-Planck-Institut für Strömungsforschung, Bunsenstrasse 10, 37073 Göttingen, Germany
2Department of Chemistry, University of Califorina, Irvine, California 92697-2025
3Department of Physical Chemistry, The Hebrew University, Jerusalem 91904, Israel
4Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138

(Received 22 November 2002; accepted 3 April 2003)

We report the production in the gas phase of ionically bound HXeI molecules. The molecules are generated by the photodissociation of HI molecules in large Xen clusters and are identified from the asymmetry of the detected H atom fragments arising from the dissociation of oriented HXeI. The orientation, resulting from a synergistic action of a pulsed laser field with a weak electrostatic field, is quite pronounced, due to a large ratio of the polarizability anisotropy to the rotational constant of HXeI. © 2003 American Institute of Physics.

© 2003 American Institute of Physics

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KEYWORDS and PACS

Keywords

hydrogen compounds, xenon compounds, photodissociation, molecular orientation, laser beam effects, electric field effects, xenon, atomic clusters, molecular clusters

PACS

  • 33.80.Gj

    Diffuse spectra; predissociation, photodissociation

  • 36.40.Jn

    Reactivity of clusters

ARTICLE DATA

Digital Object Identifier
http://dx.doi.org/10.1063/1.1577311

PUBLICATION DATA

ISSN

0021-9606 (print)  
1089-7690 (online)

Publisher

$abstract.society.value is a Member of CrossRef American Institute of Physics

For access to fully linked references, you need to log in.
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