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J. Chem. Phys. 126, 089901 (2007); http://dx.doi.org/10.1063/1.2372501 (2 pages)

Erratum: “Self-diffusion of supercritical water in extremely low-density region” [ J. Chem. Phys. 125, 074307 (2006) ]

Ken Yoshida, Nobuyuki Matubayasi, and Masaru Nakahara

Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0111, Japan

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(Received 28 September 2006; accepted 2 October 2006; published online 22 February 2007)

Abstract unavailable.

EDITORIALLY RELATED

  1. Self-diffusion of supercritical water in extremely low-density region
    Ken Yoshida et al.
    J. Chem. Phys. 125, 074307 (2006)JCPSA6000125000007074307000001

KEYWORDS and PACS

Keywords

water, self-diffusion

PACS

ARTICLE DATA

PUBLICATION DATA

ISSN

0021-9606 (print)  
1089-7690 (online)


Figures (3) Tables (1)

Figures (click on thumbnails to view enlargements)

FIG.1
The chemical shift δ plotted against temperature for the sample at the lowest density of 0.0041 g cm−3. The δ for the gas branch of the liquid-gas coexistence curve at 146 °C (0.0023 g cm−3) is set to zero. The dashed line indicates the average of the repetitions.

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FIG.2
The product of the self-diffusion coefficients of water and the density divided by square root of the temperature, ρD/math, plotted against the density at 200, 300, and 400 °C. The open symbols indicate the values on the gas-branch of the liquid-gas coexistence curve. The dashed line is linearly fitted to the experimental values and the crossed symbols indicate the values extrapolated to the zero-density limit, (ρD)0/math. At 200 °C, the ρD/math value at the lowest density of 0.0041 g cm−3 is used as the (ρD)0/math value because the steam-density region is too narrow to allow the linear fit of ρD/math against ρ.

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FIG.3
The product (ρD)0/math for water plotted against temperature. The values calculated by the Chapman-Enskog solution of the Boltzmann equation by using the LJ potential and the Stockmayer potential are taken from Refs. 2 and 36, respectively.

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Tables

Table I. The self-diffusion coefficients for water determined by (a) NMR experiment and (b) MD simulation in high-temperature and low-density conditions including supercritical.

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