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J. Chem. Phys. 4, 251 (1936); http://dx.doi.org/10.1063/1.1749831 (3 pages)
Reaction Products of Ethyl Alcohol and Sodium Hydroxide
(Received 2 February 1936)
A study has been made of the products formed when sodium hydroxide and ethyl alcohol react in the absence of water. Evidence has been found which indicates a reaction in which sodium ethylate and water are produced. Three types of tests have been made to determine the amount of water formed. The copper acetylide method, a volumetric method, and a method involving infrared absorption measurements all indicate a reaction which goes from 75 to 100 percent toward completion.
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References
G. E. Grantham, Phys. Rev. 18, 339 (1921).E. K. Plyler and C. J. Craven, J. Chem. Phys. 2, 303 (1934)JCPSA6000002000006000303000001.
E. K. Plyler and WalterGordy, J. Chem. Phys. 2, 470 (1934)JCPSA6000002000008000470000001.
E. K. Plyler and Dudley Williams, J. Chem. Phys. 2, 565 (1934)JCPSA6000002000009000565000001.
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