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J. Chem. Phys. 52, 5949 (1970); http://dx.doi.org/10.1063/1.1672878 (3 pages)

Linewidths in High‐Resolution NMR Spectra. Homogeneous Broadening Due to Intermolecular Relaxation

Stanislav Sýkora

Istituto di Chimica Industriale del Politecnico, Piazza Leonardo da Vinci 32, Milano, Italy

(Received 10 February 1970)

The effects connected with the intermolecular relaxation in the coupled nuclear systems are studied theoretically. It was shown that, because of the general properties of nuclear‐spin systems, the number of parameters necessary to describe the relaxation process is reduced substantially. Moreover, the structure of nuclear system and relaxation process parameters are to a far extent separated. This fact enables one to draw quite detailed conclusions on the energy‐level widths even without any specification of the type of intermolecular relaxation process.

© 1970 American Institute of Physics

ARTICLE DATA

PUBLICATION DATA

ISSN

0021-9606 (print)  
1089-7690 (online)

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