Jump to Content
View Cart
LOG IN or SELECT A PURCHASE OPTION:
J. Chem. Phys. 56, 1863 (1972); http://dx.doi.org/10.1063/1.1677466 (7 pages)
Thermodynamics of Hydrogen‐Isotope‐Exchange Reactions. I. Electrochemistry in Dimethylformamide
(Received 20 September 1971)
Alerts
Alert Me When Cited
Alert Me When Corrected
Tools
Download Citation
Add to MyScitation
Permissions / Reprints
Blog This Article
Print-Friendly
Research Toolkit
Share
Email Abstract
CiteULike
del.icio.us
BibSonomy
Tweet this Article
Add to FacebookThe paper reports our results for the direct experimental determination of the equilibrium constants for the hydrogen‐isotope‐exchange reaction, D2(g)+2HCl(DMF) = H2(g)+2DCl(DMF), where DMF is the solvent N,N‐dimethylformamide. The reaction was studied in electrochemical double cells without liquid junction of the type,
The experimentally determined values of E0(296.6oK) for this cell are Eion0 = 7.64±0.38 mV and Eneut0 = 8.12±0.54 mV, where Eion0 refers to strong electrolyte standard states for HCl(DMF) and DCl(DMF), and Eneut0 refers to undissociated solute standard states for HCl(DMF) and DCl(DMF). The corresponding experimental values of the equilibrium constants are Kion = 1.82±0.05 and Kneut = 1.89±0.08 (296.6oK). The experimental values of the equilibrium constants are compared with values for K calculated from statistical thermodynamic theory for model reactions.
© 1972 The American Institute of Physics
ARTICLE DATA
Digital Object Identifier
PUBLICATION DATA
Publisher
For access to fully linked references, you need to log in.
References
M. Goldblatt and W. M. Jones, J. Chem. Phys. 51, 1881 (1969)JCPSA6000051000005001881000001.For access to citing articles, you need to log in.
This Publication
Scitation
Google Scholar
PubMed